Effects of nanopore size on properties of modified inner surfaces.
نویسندگان
چکیده
By analyzing sorption isotherm curves of surface treated MCM-41 samples, it is noticed that if the nanopore size is relatively small, the end group dominates the solid-liquid interaction and the influence of the side group is relatively weak, which can be attributed to the confinement effect of nanopore walls.
منابع مشابه
Studying Performance of Dubinin-astakhov and Dubinin-raduchkevic Equations to Evaluate Nanopore Volume and Pore Size of MCM-41 Particles (TECHNICAL NOTE)
MCM-41 particles were synthesized using inorganic raw materials and Cetyltrimethylammonium bromide (CTAB). The textural properties and structure of MCM-41 particles were characterized by XRD, SEM, TEM and N2 adsorption-desorption methods. To study performance of Dubinin-Astakhov and Dubinin-Raduchkevic isotherm models in evaluating mesopore volume and pore size of MCM-41 samples, the mesopore ...
متن کاملModified infiltration of solvated ions and ionic liquid in a nanoporous carbon
Infiltration of ions in a nanoporous carbon is responsive to the external electric field. If the liquid phase is an aqueous solution of electrolyte, the effective solid-liquid interfacial tension decreases as the voltage rises, similar to the electrowetting phenomenon at a large graphite surface. If the liquid phase is an ionic liquid, however, the effective interfacial tension increases with t...
متن کاملHydrogen Peroxide Sensing Based on Inner Surfaces Modification of Solid-State Nanopore
There are many techniques for the detection of molecules. But detection of molecules through solid-state nanopore in a solution is one of the promising, high-throughput, and low-cost technology used these days. In the present investigation, a solid-state nanopore platform was fabricated for the detection of hydrogen peroxide (H2O2), which is not only a label free product but also a significant ...
متن کاملGeometric Effects on Nanopore Creation in Graphene and on the Impact-withstanding Efficiency of Graphene Nanosheets
Abstract Single- and multilayer graphene sheets (MLGSs) are projectile-resisting materials that can be bombarded by nanoparticles to produce graphene sheets of various sizes and distributions of nanopores. These sheets are used in a variety of applications, including DNA sequencing, water desalination, and phase separation. Here, the impact-withstanding efficiency of graphene nanosheets and the...
متن کاملAntigen Detection via the Rate of Ion Current Rectification Change of the Antibody-Modified Glass Nanopore Membrane
Ion current rectification (ICR), defined as an increase in ion conduction at a given polarity and a decrease in ion conduction for the same voltage at the opposite polarity, i.e., a deviation from a linear ohmic response, occurs in conical shaped pores due to the voltage dependent solution conductivity within the aperture. The degree to which the ionic current rectifies is a function of the siz...
متن کاملذخیره در منابع من
با ذخیره ی این منبع در منابع من، دسترسی به آن را برای استفاده های بعدی آسان تر کنید
برای دانلود متن کامل این مقاله و بیش از 32 میلیون مقاله دیگر ابتدا ثبت نام کنید
ثبت ناماگر عضو سایت هستید لطفا وارد حساب کاربری خود شوید
ورودعنوان ژورنال:
- Langmuir : the ACS journal of surfaces and colloids
دوره 23 23 شماره
صفحات -
تاریخ انتشار 2007